共价有机骨架
光催化
贵金属
过渡金属
共价键
磷化物
材料科学
可见光谱
催化作用
分解水
贵金属
金属
纳米技术
化学工程
化学
有机化学
光电子学
冶金
工程类
作者
Ge Yan,Xiaodong Sun,Kailai Zhang,Yu Zhang,Hui Li,Yuhai Dou,Ding Yuan,Hongwei Huang,Baohua Jia,Hao Li,Tianyi Ma
出处
期刊:Small
[Wiley]
日期:2022-05-25
卷期号:18 (25)
被引量:33
标识
DOI:10.1002/smll.202201340
摘要
Abstract 2D covalent organic frameworks (COFs) are considered as one kind of the most promising crystalline porous materials for solar‐driven hydrogen production. However, adding noble metal co‐catalysts into the COFs‐based photocatalytic system is always indispensable. Herein, through a simple solvothermal synthesis method, TpPa‐1‐COF, a typical 2D COF, which displays a wide light absorption region, is rationally combined with transition metal phosphides (TMPs) to fabricate three TMPs/TpPa‐1‐COF hybrid materials, named Ni 12 P 5 (Ni 2 P or CoP)/TpPa‐1‐COF. The incorporated TMPs can be served as electron collectors for accelerating the transfer of charges on TpPa‐1‐COF, thus the composites are demonstrated to be efficient photocatalysts for promoting water splitting. Benefitting from the richer surface reactive sites and lower H* formation energy barrier, the Ni 12 P 5 can most effectively improve the photocatalytic performance of the TpPa‐1‐COF, and the H 2 evolution rate can reach up to 31.6 µmol h −1 , approximately 19 times greater than pristine TpPa‐1‐COF (1.65 µmol h −1 ), and is comparable to the Pt/TpPa‐1‐COF (38.8 µmol h −1 ). This work is the first example of combining COFs with TMPs to construct efficient photocatalysts, which may offer new insight for constructing noble‐metal‐free COF‐based photocatalysts.
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