| 标题 |
Catalytic de-chlorination of products from PVC degradation by magnetite (Fe3O4) 磁铁矿(Fe3O4)对PVC降解产物的催化脱氯
相关领域
磁铁矿
降级(电信)
催化作用
化学
化学工程
材料科学
冶金
有机化学
计算机科学
工程类
电信
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| 其它 | This contribution provides a systematic theoretical thermo-kinetic study of the initial reactions between Fe 3 O 4 (111) surface, as a representative model for metal oxides in electric arc furnace dust (EAFD) with HCl and selected chlorinated hydrocarbons, as major products from thermal degradation of PVC. Formation of the experimentally observed iron chloride occurs by subsequent dissociative addition of HCl molecules followed by H migration into a surface hydroxyl group. |
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