Lead-Free Textured Ceramics with Ultrahigh Piezoelectric Properties by Synergistic Design

Lead-free ceramics with superior piezoelectric performance are highly desirable in various electromechanical applications. Unfortunately, it is still challenging to achieve significantly enhanced piezoelectricity without sacrificing the Curie temperature (Tc) in current BaTiO3-based ceramics. To address this issue, a synergistic design strategy of integrating crystallographic texture, multiphase coexistence, and doping engineering is proposed here. Highly [001]c-textured (Ba0.95Ca0.05)(Ti0.92Zr0.06Sn0.02)O3 ceramics are synthesized through Li-related liquid-phase-assisted templated grain growth, with improved grain orientation quality (f of ∼96% and r of ∼0.16) achieved at substantially reduced texture temperatures. Encouragingly, ultrahigh comprehensive piezoelectric properties, i.e., piezoelectric coefficient d33 of ∼820 pC N–1, electrostrain Smax/Emax of ∼2040 pm V–1, and figure of merit d33 × g33 of ∼23.5 × 10–12 m2 N–1, are simultaneously obtained without sacrificing Tc, which are also about 2.3, 2.4, and 4.3 times as high as those of non-textured counterpart, respectively. On the basis of the experiments and theoretical modeling, the outstanding piezoelectric performance is attributed to more effective exploration of property anisotropy and easier polarization rotation/extension, owing to improved grain orientation quality, dissolution of templates into oriented grains, coexisting R + O + T phases, and domain miniaturization. This work provides important guidelines for developing novel ceramics with outstanding piezoelectric properties and can largely expand application fields of textured BaTiO3-based ceramics into high-performance and multilayer electronic devices.