分子内力
烯烃
化学
炔烃
联轴节（管道）
立体化学
组合化学
有机化学
催化作用
机械工程
工程类
作者
Xiandie Zhang,Xiuying Liu,Xiaoli Li,Yini Wang,Rui He,Guofu Zhong,Jian Zhang
标识
DOI：10.1021/acs.orglett.5c01106
摘要
The first iridium-catalyzed intramolecular alkene/alkyne cross-coupling reaction has been developed to prepare a wide range of 12- to 26-membered macrocyclic 1,3-dienes. This operationally simple protocol proceeded by NHTs amide-enabled alkenyl C-H functionalization and exhibited wide functionality tolerance and excellent E/Z ratio selectivity.
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