塔菲尔方程
过电位
电催化剂
析氧
分解水
催化作用
腐蚀
无定形固体
材料科学
非晶态金属
合金
阴极保护
丝带
氧气
冶金
化学工程
无机化学
化学
电化学
复合材料
物理化学
电极
结晶学
有机化学
工程类
光催化
生物化学
作者
Xiying Jian,Jian Li,Bing Han,Fei Chu,Kaiyao Wu,Yuying Meng,Meng Zhang,Huaijun Lin
标识
DOI:10.1016/j.jnoncrysol.2022.122117
摘要
In this work, different amounts of FeOOH are in situ generated on an amorphous Fe78Si9B13 alloy ribbon by potentiostatic cathodic corrosion treatments for different time, including 0.5 h, 1 h, 2 h and 5 h, which are marked as the R-0.5h, R-1h, R-2h and R-5h, respectively. Afterwards, the corroded samples are investigated as electrocatalysts for the oxygen evolution reaction (OER) of water splitting in 1 M KOH. An appropriate amount of FeOOH not only provides more active sites, but also generates hydroxy1 radicals (OH˙) to greatly improve the efficiency of electronic transmission. However, when the surface of samples is covered by the thick and dense FeOOH layer, the catalytic reaction rate sharply decreases. The R-1h sample shows the best OER catalytic performances, which can achieve an overpotential of 356 mV at a current density of 10 mA cm−2 and the Tafel slope of 45 mV dec−1.
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