MXenes公司
材料科学
光热治疗
能量转换效率
光热效应
纳米技术
蒸发
化学工程
光电子学
热力学
物理
工程类
作者
Tong Xu,Shujuan Tan,Shaoxiong Li,Tianyu Chen,Yue Wu,Yilin Hao,Chengyan Liu,Guangbin Ji
标识
DOI:10.1002/adfm.202400424
摘要
Abstract Optimizin the efficient light‐trapping in the photothermal conversion by enhancing localized surface plasmon resonance (LSPR) is crucial in improving light‐heat‐conversion efficiency of Ti 3 C 2 T x MXene. However, its susceptibility to oxidation makes it prone to oxides formation, diminishing its metallic properties and significantly reducing the LSPR effect. This work synthesizes a kind of air‐stable hybrid Ti 3 C 2 T x MXenes by a synergistic densification strategy that incorporates sulfhydryl‐bonding between organic and inorganic parts by reacting Ti 3 C 2 T x MXene with thiocarboxylic acids. The resultant shortening of electron transport pathways, enhanced charge density, and the generation of additional electronic states around the Fermi level collectively contribute to an augmented LSPR effect. Additionally, the hybrid Ti 3 C 2 T x MXenes also demonstrate high‐temperature resistance and reduced water interactions. These combined effects substantially elevate photothermal conversion efficiency through thiocarboxylic acids modification, reaching a photothermal evaporation rate of 1.77 kg m −2 h −1 with 94.56% efficiency in hybrid Ti 3 C 2 T x MXenes. The approach paves the way for the design and development of a three‐in‐one strategy for photothermal conversion.
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