Microcrystalline Engineering of Anthracite‐Based Carbon Via Salt‐Assisted Ball Milling for Enhanced Sodium Storage Performance

Abstract Coal‐based carbon material, characterized by abundant resources and low cost, has gained considerable interests as a promising anode candidate for sodium‐ion batteries (SIBs). However, the coal‐based carbon generally shows inferior Na‐storage performance due to its highly‐ordered microstructure with narrow interlayer spacing. Herein, a salt‐assisted mechanical ball‐milling strategy is proposed to disrupt the polycyclic aromatic hydrocarbon structure in anthracite molecules, thereby reducing the microcrystalline regularity of the derived carbon during following pyrolysis process. In addition, the induced C ─ O ─ C bonds during ball‐milling process can alter the pyrolysis behavior of anthracite and restrain the formation of surface defects. Consequently, in contrast to pristine anthracite‐based pyrolytic carbon, which exhibits a Na‐storage capacity of 198.4 mAh g −1 with a low initial Coulombic efficiency (ICE) of 65.1%, the ball‐milling modified carbon assisted by NaCl salt (NAC), with enhanced structural disordering and reduced surface defects, demonstrate significantly improved Na‐storage capacity of 332.1 mAh g −1 and ICE value of 82.0%. The NAC electrode also realizes excellent cycle and rate performance, retaining a capacity of 196.0 mAh g −1 at 1 C after 1000 cycles. Furthermore, when coupled with NaNi 1/3 Fe 1/3 Mn 1/3 O 2 cathode, the assembled Na‐ion full cell deliveres an exceptional electrochemical performance, highlighting its promising prospect as high‐performance anode for SIBs.