Exfoliated 2D Nanosheet‐Based Conjugated Polymer Composites with P‐N Heterojunction Interfaces for Highly Efficient Electrocatalytic Hydrogen Evolution

We have achieved a significant breakthrough in the preparation and development of two-dimensional nanocomposites with P-N heterojunction interfaces as efficient cathode catalysts for electrochemical hydrogen evolution reaction (HER) and iodide oxidation reaction (IOR). P-type acid-doped polyaniline (PANI) and N-type exfoliated molybdenum disulfide (MoS₂) nanosheets can form structurally stable composites due to formation of P-N heterojunction structures at their interfaces. These P-N heterojunctions facilitate charge transfer from PANI to MoS₂ structures and thus significantly enhance the catalytic efficiency of MoS₂ in the HER and IOR. Herein, by combining efficient sodium-functionalized chitosan-assisted MoS₂ exfoliation, electropolymerization of PANI on nickel foam (NF) substrate, and electrochemical activation, controllable and scalable Na-Chitosan/MoS₂/PANI/NF electrodes are successfully constructed as non-noble metal-based electrochemical catalysts. Compared to a commercial platinum/carbon (Pt/C) catalyst, the Na-Chitosan/MoS₂/PANI/NF electrode exhibits significantly lower resistance and overpotential, a similar Tafel slope, and excellent catalytic stability at high current densities, demonstrating excellent catalytic performance in the HER under acidic conditions. More importantly, results obtained from proton exchange membrane fuel cell devices confirm the Na-Chitosan/MoS₂/PANI/NF electrode exhibits a low turn-on voltage, high current density, and stable operation at 2 V. Thus, this system holds potential as a replacement for Pt/C with feasibility for applications in energy-related fields.