聚酯纤维
位阻效应
催化作用
材料科学
聚合
金属
丙交酯
石油化工
开环聚合
共聚物
高分子化学
有机化学
化学
聚合物
作者
Eduard Glöckler,Sujit Kumar Ghosh,Stephan Schulz
标识
DOI:10.1080/15583724.2022.2121837
摘要
This review highlights the ongoing developments on the ring-opening polymerization (ROP) of lactide (LA) and caprolactone (CL) using mononuclear and dinuclear β-diketiminate- and β-ketoiminate-substituted metal complexes. The resulting aliphatic polyesters are of great interest as sustainable replacements to petrochemicals-based polymers with potential applications in tissue engineering, bio-medical, and agricultural sciences. β-Diketiminate and β-ketoiminate metal complexes are very promising ROP catalysts since their steric and electronic properties, and hence their catalytic activity and selectivity can be easily modified. This review compares different classes of β-diketiminate and β-ketoiminate complexes with respect to the controlled synthesis of homopolymers and copolymers of aliphatic polyesters and elaborates on the polymerization kinetics and mechanistic studies.
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