Towards the Sustainable Production of Ultra-Low-Sulfur Fuels through Photocatalytic Oxidation

Nowadays, the sulfur-containing compounds are removed from motor fuels through the traditional hydrodesulfurization technology, which takes place under harsh reaction conditions (temperature of 350–450 °C and pressure of 30–60 atm) in the presence of catalysts based on alumina with impregnated cobalt and molybdenum. According to the principles of green chemistry, energy requirements should be recognized for their environmental and economic impacts and should be minimized, i.e., the chemical processes should be carried out at ambient temperature and atmospheric pressure. This approach could be implemented using photocatalysts that are sensitive to visible light. The creation of highly active photocatalytic systems for the deep purification of fuels from sulfur compounds becomes an important task of modern catalysis science. The present critical review reports recent progress over the last 5 years in heterogeneous photocatalytic desulfurization under visible light irradiation. Specific attention is paid to the methods for boosting the photocatalytic activity of materials, with a focus on the creation of heterojunctions as the most promising approach. This review also discusses the influence of operating parameters (nature of oxidant, molar ratio of oxidant/sulfur-containing compounds, photocatalyst loading, etc.) on the reaction efficiency. Some perspectives and future research directions on photocatalytic desulfurization are also provided.