材料科学
海水
电池(电)
膜
纳米技术
海洋学
热力学
地质学
功率(物理)
物理
遗传学
生物
作者
Wei Wen,Chao Geng,Xinran Li,Hongpeng Li,Jin‐Ming Wu,Hisayoshi Kobayashi,Tulai Sun,Zhenyu Zhang,Dongliang Chao
标识
DOI:10.1002/adma.202312343
摘要
Abstract Seawater batteries that directly utilize natural seawater as electrolytes are ideal sustainable aqueous devices with high safety, exceedingly low cost, and environmental friendliness. However, the present seawater batteries are either primary batteries or rechargeable half‐seawater/half‐nonaqueous batteries because of the lack of suitable anode working in seawater. Here, we demonstrate a unique lattice engineering to unlock the electrochemically inert anatase TiO 2 anode to be highly active for the reversible uptake of multiple cations (Na + , Mg 2+ , and Ca 2+ ) in aqueous electrolytes. Density functional theory calculations and in‐situ Raman further reveal the origin of the unprecedented charge storage behaviors, which can be attributed to the significant reduction of the cations diffusion barrier within the lattice, i.e., from 1.5 eV to 0.4 eV. As a result, the capacities of anatase TiO 2 with 2.4% lattice expansion are ca. 100 times higher than the routine one in natural seawater, and ca. 200 times higher in aqueous Na + electrolyte. The finding should significantly advance aqueous seawater energy storage devices closer to practical applications. This article is protected by copyright. All rights reserved
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