分散性
纳米团簇
纳米技术
材料科学
跨国公司
纳米颗粒
金属
高分子化学
业务
财务
冶金
作者
Yong Yu,Qiaofeng Yao,Zhentao Luo,Xun Yuan,Jim Yang Lee,Jianping Xie
出处
期刊:Nanoscale
[The Royal Society of Chemistry]
日期:2013-01-01
卷期号:5 (11): 4606-4606
被引量:99
摘要
In very recent years, thiolate-protected metal nanoclusters (or thiolated MNCs) with core sizes smaller than 2 nm have emerged as a new direction in nanoparticle research due to their discrete and size dependent electronic structures and molecular-like properties, such as HOMO–LUMO transitions in optical absorptions, quantized charging, and strong luminescence. Synthesis of monodisperse thiolated MNCs in sufficiently large quantities (up to several hundred micrograms) is necessary for establishing reliable size–property relationships and exploring potential applications. This Feature Article reviews recent progress in the development of synthetic strategies for the production of monodisperse thiolated MNCs. The preparation of monodisperse thiolated MNCs is viewed as an engineerable process where both the precursors (input) and their conversion chemistry (processing) may be rationally designed to achieve the desired outcome – monodisperse thiolated MNCs (output). Several strategies for tailoring the precursor and the conversion process are analyzed to arrive at a unifying understanding of the processes involved.
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