甲醛
硫脲
吸附
螯合作用
化学
核化学
螯合树脂
无机化学
水溶液中的金属离子
傅里叶变换红外光谱
金属
有机化学
化学工程
工程类
作者
Zeliyha Çelik,Mustafa Gülfen,Ali Aydın
标识
DOI:10.1016/j.jhazmat.2009.09.087
摘要
In this study, a new chelating resin of dithiooxamide (rubeanic acid)–formaldehyde (DTOF) has been synthesized by the reaction of dithiooxamide and formaldehyde. Also a well-known chelating resin of thiourea (thiooxamide)–formaldehyde (TUF) has been prepared by the reaction of thiourea and formaldehyde. DTOF and TUF chelating resins were used in the adsorption, separation and concentration of silver ions by batch and column techniques. These resins were characterized using FTIR and elemental analysis. It was found that DTOF resin has silver adsorption capacity of 3333.3 mg g−1 or 30.86 mmolg g−1 and TUF resin has the capacity of 1428.6 mg g−1 or 13.22 mmol g−1. DTOF resin showed more affinity to silver ions according to Cu(II), Zn(II), Ni(II) and Co(II) base metal ions than TUF resin. It was also demonstrated that DTOF resin can be used in the separation and concentration of silver ions.
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