有机发光二极管
三元运算
接受者
掺杂剂
荧光
材料科学
三嗪
热稳定性
光电子学
化学
光化学
兴奋剂
图层(电子)
高分子化学
纳米技术
有机化学
计算机科学
程序设计语言
物理
量子力学
凝聚态物理
作者
Ting Xu,Guohua Xie,Taian Huang,He Li,Xiaosong Cao,Yang Tang,Chuluo Yang
标识
DOI:10.1016/j.orgel.2021.106184
摘要
A series of novel binary and ternary components of the exciplexes as the cohosts for a red thermally activated delayed fluorescence (TADF) dopant were investigated in the solution-processed OLEDs, where 1,3-bis[(4-tert-butylphenyl)-1,3,4-oxadiazolyl] phenylene (OXD-7) as a conventional acceptor, and 1,3-bis(carbazol-9-yl)benzene (mCP) as a conventional donor were respectively mixed with two molecules containing spirofluorene and s-triazine moieties (TDP-TRZ or DTDP-TRZ) with excellent thermal stability and high electron mobility as the second acceptors. Particularly, the power efficiencies of the devices with the exciplexes are generally enhanced via this strategy of host engineering. The designed devices could achieve a percentage increase of 179% in the power efficiency, compared with the reference device with single-component host, mainly owing to the synergistic effects of electron block, balanced injection of charge carriers and efficient exciton harvesting. The working mechanism of energy transfer in binary and ternary components of the exciplexes hosted red TADF OLEDs is studied. This work provides a novel device design philosophy with the multiple exciplexes cohosts for solution-processed TADF OLEDs, which would help to simplify the fabrication processing, lower the cost, and popularize OLED technology.
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