三嗪
共价键
多孔性
催化作用
化学工程
纳米技术
材料科学
制作
聚合
组合化学
化学
有机化学
聚合物
医学
工程类
病理
替代医学
作者
Tian Sun,Yan Liang,Wenjia Luo,Lei Zhang,Xiaofeng Cao,Yuxi Xu
标识
DOI:10.1002/ange.202203327
摘要
Abstract Scalable and eco‐friendly synthesis of crystalline porous covalent triazine frameworks (CTFs) is essential to realize their broad industrial applications but remains a great challenge, which requires the fundamental understanding of the two‐dimensional polymerization mechanism. Herein, we report a universal polyphosphoric acid (H 6 P 4 O 13 )‐catalyzed nitrile trimerization route to synthesize a series of highly crystalline CTFs with high specific surface areas. This new strategy enables the cost‐effective large‐scale fabrication of crystalline CTFs at kilogram level for the first time. Through density functional theory calculation and detailed controlled experiments, we reveal that the polyphosphate acid show much higher catalytic activity for trimerization reaction than its analogues such as P 2 O 5 and H 3 PO 4 . Furthermore, the crystalline CTFs with regular porosity and abundant triazine groups exhibit ultrahigh removal efficiency of micropollutants, indicating its great potential in environment remediation.
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