光催化
石墨氮化碳
材料科学
杂原子
氮化碳
带隙
制氢
光催化分解水
分解水
氢
热液循环
催化作用
化学工程
可见光谱
纳米技术
氮化物
光化学
X射线光电子能谱
碳纤维
兴奋剂
光电子学
复合材料
化学
有机化学
工程类
复合数
图层(电子)
戒指(化学)
作者
Hao Wang,Bo Wang,Yaru Bian,Liming Dai
标识
DOI:10.1021/acsami.7b02445
摘要
The generation of clean hydrogen gas from photocatalytic water splitting by using graphitic carbon nitride (g-C3N4) as the photocatalyst has attracted considerable research interest. For practical applications, however, the photocatalytic activity of g-C3N4 needs to be further improved by, for example, band gap engineering through heteroatom doping. In this study, we found that doping of carbon nitride with carbon and phosphorus (P) could tune energy level of the conduction band. Subsequent hydrothermal treatment led to an increase in the specific surface area from 24.9 up to 141.1 m2 g–1, which was accompanied by increasing C concentration of the resultant C, P-doped g-C3N4 to reduce the hole–electron recombination and enhance the conductivity. Consequently, the C, P-codoped g-C3N4 (i.e., CPCN-1*) exhibited a much enhanced photocatalytic activity for efficient generation of H2 by photocatalytic water splitting under visible-light irradiation (1493.3 μmol g–1 h–1—about 9.7 times enhancement from that of bulk g-C3N4).
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