转鼓
吲哚试验
电泳剂
环氧化物
试剂
亲核细胞
化学
组合化学
亲电取代
立体化学
有机化学
催化作用
作者
Takumi Abe,Koji Yamada,Takahide Nishi
出处
期刊:Yūki Gōsei Kagaku Kyōkaishi
[The Society of Synthetic Organic Chemistry, Japan]
日期:2020-06-01
卷期号:78 (6): 597-607
被引量:7
标识
DOI:10.5059/yukigoseikyokaishi.78.597
摘要
C3-Nucleophilic substitution of indoles has been limited because the transformation requires an umpolung of the C3 position of indoles. Among the indole derivatives, indole-2,3-epoxides could be potentially be used as C3-electrophilic reagents due to the electrophilic nature of the C2 and C3 positions. However, their use as C3 electrophilic reagents has not been possible so far due to their instability.
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