材料科学
阴极
电化学
复合数
堆积
水溶液
电流密度
化学工程
纳米技术
电导率
超级电容器
电容
复合材料
电极
电气工程
化学
物理
有机化学
物理化学
量子力学
工程类
作者
Luan Fang,Lin Liu,Zhuomei Wu,Tianhao Xu,Xuxu Wang,Limin Chang,Ping Nie
出处
期刊:Nanomaterials
[MDPI AG]
日期:2023-05-03
卷期号:13 (9): 1536-1536
被引量:1
摘要
Due to their reliability, affordability and high safety, rechargeable aqueous zinc ion batteries (ZIBs) have garnered a lot of attention. Nevertheless, undesirable long-term cycle performance and the inadequate energy density of cathode materials impede the development of ZIBs. Herein, we report a layered CaV4O9-MXene (Ti3C2Tx) composite assembled using CaV4O9 nanosheets on Ti3C2Tx and investigate its electrochemical performance as a new cathode for ZIBs, where CaV4O9 nanosheets attached on the surface of MXene and interlamination create a layered 2D structure, efficiently improving the electrical conductivity of CaV4O9 and avoiding the stacking of MXene nanosheets. The structure also enables fast ion and electron transport. Further discussion is conducted on the effects of adding MXene in various amounts on the morphology and electrochemical properties. The composite shows an improved reversible capacity of 274.3 mA h g-1 at 0.1 A g-1, superior rate capabilities at 7 A g-1, and a high specific capacity of 107.6 mA h g-1 can be delivered after 2000 cycles at a current density of 1 A g-1. The improvement of the electrochemical performance is due to its unique layered structure, high electrical conductivity, and pseudo capacitance behavior.
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