Applicability of a graphene oxide nanocomposite for fabrication of an electrochemical sensor for simultaneous detection of sunset yellow and rhodamine B in food samples

Developing a sensitive portable sensor for the determination of food additives is very important. Herein, a simple and sensitive electrochemical sensor has been constructed based on a carbon paste electrode (CPE) modified with graphene oxide (GO) nanosheets for the simultaneous determination of sunset yellow (SY) and rhodamine B (RhB) in phosphate buffer solution (pH = 4). The cyclic and differential pulse voltammetry (CV and DPV) results revealed two well-resolved anodic peaks for SY and RhB with a remarkable increase in oxidation signals of these colorants. Based on this, an electrochemical method was developed for the first time for the simultaneous detection of SY and RhB. Applicability of the sensor was confirmed in various concentrations of two analytes in two linear ranges of 1-20 μM for SY and 1-30 μM for RhB with a limit of detection (LOD) of 10.0 nM and 20.0 nM, respectively. Furthermore, the proposed sensor was successfully employed for the simultaneous detection of SY and RhB in food samples with recoveries of 93.1-106.0% indicating promising potential in practical application.