渗透(HVAC)
材料科学
介观物理学
纳米技术
复合材料
物理
量子力学
作者
Carys Worsley,Tom Dunlop,Sarah‐Jane Potts,Rodrigo García-Rodríguez,Rebecca S. Bolton,Matthew L. Davies,Eifion Jewell,Trystan Watson
出处
期刊:ACS applied energy materials
[American Chemical Society]
日期:2024-02-24
卷期号:7 (5): 1938-1948
被引量:1
标识
DOI:10.1021/acsaem.3c03056
摘要
Mesoscopic carbon-based perovskite solar cells (CPSCs) are often cited as a potential frontrunner to perovskite commercialization. Infiltration, the extent to which perovskite fills the mesoporous scaffold, is critical for optimum performance and stability. However, infiltration data are usually presented as qualitative photographic comparisons of samples with extreme infiltration variation. This work examines how small infiltration defects impact performance using an optical microscopy examination of the base TiO2 layer to identify issues and develop targeted techniques for infiltration enhancement. Critically, the uninfiltrated area at the base of the stack was found to correlate well with PCE across multiple batches of varied print quality and ZrO2 thickness. Through reduction of mesh mark defects and improvement of print quality in the ZrO2 and carbon layers, a champion PCE of 15.01% is attained. It follows that this facile, multiscaled, nondestructive technique could enable targeted performance enhancement and quality control in future scale-up initiatives.
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