Discriminating the Active Ru Species Towards the Selective Generation of Singlet Oxygen from Peroxymonosulfate: Nanoparticles Surpass Single‐Atom Catalysts

Abstract Singlet oxygen ( 1 O 2 ) is an exceptional reactive oxygen species in advanced oxidation processes for environmental remediation. Despite single‐atom catalysts (SACs) representing the promising candidate for the selective generation of 1 O 2 from peroxymonosulfate (PMS), the necessity to meticulously regulate the coordination environment of metal centers poses a significant challenge in the precisely‐controlled synthetic method. Another dilemma to SACs is their high surface free energy, which results in an inherent tendency for the surface migration and aggregation of metal atoms. We here for the first time reported that Ru nanoparticles (NPs) synthesized by the facile pyrolysis method behave as robust Fenton‐like catalysts, outperforming Ru SACs, towards efficient activation of PMS to produce 1 O 2 with nearly 100 % selectivity, remarkably improving the degradation efficiency for target pollutants. Density functional theory calculations have unveiled that the boosted PMS activation can be attributed to two aspects: (i) enhanced adsorption of PMS molecules onto Ru NPs, and (ii) decreased energy barriers by offering adjacent sites for promoted dimerization of *O intermediates into adsorbed 1 O 2 . This study deepens the current understanding of PMS chemistry, and sheds light on the design and optimization of Fenton‐like catalysts.