锂(药物)
纳米颗粒
材料科学
碳纤维
氮气
兴奋剂
纳米技术
期限(时间)
化学工程
无机化学
化学
有机化学
复合材料
复合数
光电子学
医学
物理
量子力学
内分泌学
工程类
作者
Shaochen Wang,Menglei Guo,Chenwei Qu,Jun Wen,Dongsheng Yang,Guoyong Huang,Shengming Xu,Fengshan Yu,Yuanhua Zhang,Yunlong Wang
标识
DOI:10.1016/j.jallcom.2024.174417
摘要
The significant volume change and low conductivity are the primary challenges to effectively utilizing transition metal sulfide anode materials for lithium-ion batteries. Given that, this study presents a facile non-template method for synthesizing nitrogen-doped carbon-coated CoS2 (CoS2@NC) nanoparticle composites with diverse morphologies. The morphology of the ZIF-67 precursor was controlled by employing different anionic salts, followed by carbonization and sulfurization processes under a nitrogen atmosphere to obtain the desired CoS2@NC composites (1-3 μm). The hollow CoS2@NC (H-CoS2@NC) provides more buffering space, effectively releasing the stress caused by volume changes. H-CoS2@NC composites demonstrate excellent lithium storage performance when used as anode materials for lithium-ion batteries, in stark contrast to the comparatively subpar performance of the composite derived from rhombic dodecahedrons CoS2@NC (D-CoS2@NC). At 500 mA·g-1, the initial theoretical specific capacity of H-CoS2@NC reached 601.8 mAh·g-1. Furthermore, after 350 cycles, the capacity remained at 544.6 mAh·g-1, with a capacity retention rate of 90.5%, and the H-CoS2@NC retained its original morphology intact. The protection provided by the nitrogen-doped carbon material and its favorable morphology result in outstanding lithium storage performance of H-CoS2@NC electrode.
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