环丁砜
溶剂
化学
二乙烯三胺
体积热力学
相(物质)
吸收(声学)
胺气处理
化学工程
有机化学
材料科学
热力学
复合材料
物理
工程类
作者
Rujie Wang,Lei Jiang,Qiangwei Li,Ge Gao,Shihan Zhang,Lidong Wang
出处
期刊:Energy
[Elsevier]
日期:2020-11-01
卷期号:211: 118667-118667
被引量:29
标识
DOI:10.1016/j.energy.2020.118667
摘要
Because of phase separation characteristics, biphasic solvents are recognized as promising absorbents for CO2 capture with low regeneration heat consumption. However, limited CO2 loading in CO2-rich phase, associated with excessive CO2-rich phase volume, challenges the energy-saving regeneration potential of mixed-amine biphasic solvents. In this study, sulfolane was employed as a phase splitter to improve the phase separation properties of N,N-diethylenetriamine (DETA)-N,N,N′,N″,N″-pentamethyldiethylenetriamine (PMDETA) biphasic absorbent. By introducing the hydrophobic sulfolane, large CO2 capacity (increased from 3.56 to 6.48 mol/L) and low CO2-rich phase volume (decreased from 100% to 27.1%) were simultaneously achieved. Moreover, sulfolane acted as an absorption accelerator to increase the CO2 absorption rate in DETA-PMDETA-sulfolane solvent to 1.3 times the corresponding DETA-PMDETA solvent. Benefiting from the large CO2 capacity associated with favorable phase separation behavior, DETA-PMDETA-sulfolane has a minimized regeneration heat estimated at 1.86 GJ/t-CO2 at a lean CO2-loading of 0.55 mol/mol. This is 53.4% lower than the regeneration heat (3.99 GJ/t-CO2) using 5 M monoethanolamine solvent.
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