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Microstructure and properties of MgMoNbFeTi2Yx high entropy alloy coatings by laser cladding

材料科学 微观结构 涂层 压痕硬度 腐蚀 合金 包层(金属加工) 冶金 高熵合金 固溶体 复合材料
作者
Zhen Gu,Pu Mao,Yifan Gou,Chao Yan,Shengqi Xi
出处
期刊:Surface & Coatings Technology [Elsevier BV]
卷期号:402: 126303-126303 被引量:68
标识
DOI:10.1016/j.surfcoat.2020.126303
摘要

High-entropy alloys (HEAs) are promising as a new type of engineering material with extensive research value. Rare-earth elements are widely studied and used to prepare HEAs because of their unique properties. In this work, the MgMoNbFeTi2Yx (x = 0, 0.4%, 0.8% 1.2%) HEA coatings were manufactured by laser cladding technology. The effect of Y on the phase structure, microstructure, wear resistance, microhardness and corrosion resistance of the laser cladding coatings were investigated methodically. As a result, the coating samples exhibit brilliant bonding abilities between substrates and claddings layer with Y additives. When Y content is low, the phase composition consists of a face centered cubic (FCC; Mg, Ti-rich (Nb, Ti) C carbide) and biphasic body centered cubic (BCC) solid solution. With an increment in Y content (Y = 0.8%/1.2%), the phase composition is composed by one BCC phase along with FCC. In the simulated saturated saline cement solution, corrosion resistance of the HEA coating is enhanced by Y addition. In addition, the MgMoNbFeTi2Y0.8% HEA coating show an excellent corrosion resistance. The MgMoNbFeTi2Y1.2% HEA coating displays the highest average microhardness of about 1046 HV0.3, which is 2.7 times stronger than that of the coating without Y content (Y = 0) and more than 5 times higher than that of the average microhardness of the base material. More interesting, such HEA coating shows an excellent wear resistance. This work can provide a novel and effective approach to significantly improve the surface quality of the characteristics of HEAs, which will promote them further applications as a promising candidate material in advanced manufacturing fields.

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