催化作用
级联
酶
金属
组合化学
酶催化
生物催化
化学
材料科学
有机化学
纳米技术
反应机理
色谱法
作者
Xiaoyang Li,Xun Cao,Jiarong Xiong,Jun Ge
出处
期刊:Small
[Wiley]
日期:2019-08-29
卷期号:16 (15)
被引量:40
标识
DOI:10.1002/smll.201902751
摘要
Abstract Enzyme–metal hybrid catalysts (EMHCs), which combine enzymatic and metal catalysis, provide tremendous possibilities for new chemoenzymatic cascade reactions. Here, an overview of the representative achievements in the design of EMHCs and their applications in chemoenzymatic cascade reactions are presented. The preparation of hybrid catalysts is classified into two categories: coimmobilized enzyme–metal heterogeneous catalysts and carrier‐free enzyme–metal bioconjugates. Examples of one‐pot chemoenzymatic cascade processes catalyzed by the hybrid catalysts are then provided as potential applications. Finally, the limitations and future perspectives of EMHCs are discussed.
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