超级电容器
材料科学
杂原子
石墨烯
电容
纳米技术
电导率
化学工程
多孔性
储能
氧化物
电极
碳纤维
比表面积
电解质
复合材料
复合数
化学
有机化学
催化作用
戒指(化学)
量子力学
功率(物理)
物理化学
冶金
工程类
物理
作者
Fei Mo,Hongxue Zhang,Yangxin Wang,Chunxia Chen,Xiaoliang Wu
标识
DOI:10.1016/j.est.2022.104122
摘要
Hierarchical porous carbon shows enormous potential in the field of energy storage due to the open three-dimensional (3D) interconnected porous structure, high porosity, high surface area and excellent conductivity. Herein, we develop a facile strategy to prepare heteroatom-doped hierarchical porous carbon derived from electrostatic self-assembly of chitosan and graphene oxide using potassium citrate as activator. The optimized hierarchical porous carbon exhibits well-developed 3D hierarchical porous framework, large specific surface area and massive nitrogen (4.17 at.%) and oxygen (18.33 at.%) functional groups. Due to their synergistic effect, the NGCA-600 electrode delivers a high specific capacitance of 406 F g –1 at 0.5 A g –1, good rate characteristic and superior cycle stability. Interestingly, the assembled NGCA-600//NGCA-600 all-solid-state symmetrical supercapacitor delivers a large energy density of 14.7 W h kg−1 and superior cycle stability in PVA/KOH gel electrolyte. The above results fully illustrate that the obtained hierarchical porous carbon have broad application prospects in supercapacitors.
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