阳离子聚合
吸附
高分子化学
亚甲蓝
聚合物
材料科学
化学
朗缪尔吸附模型
多孔性
化学工程
有机化学
催化作用
光催化
工程类
作者
Gang Xiong,Shan Gao,Qian Zhang,Bao-Yi Ren,Li-Xin You,Fu Ding,Yongke He,Yizhen Sun
出处
期刊:Polymer
[Elsevier]
日期:2022-04-01
卷期号:247: 124787-124787
被引量:11
标识
DOI:10.1016/j.polymer.2022.124787
摘要
Inspired by triptycene unit, the rigid paddle wheel compounds tris(o-phenylenedioxy)cyclotriphosphazene (TPP) and tris(2, 3-naphthalenedioxy)cyclotriphosphazene (TNP) were synthesized and employed as core building blocks to construct high porosity hyper-crosslinked polymers (HCP-TPP and HCP-TNP) via Friedel-Crafts alkylation reaction with formaldehyde dimethyl acetal (FDA). The bulk of HCP-TPP and HCP-TNP were comprised of nano-particles and exhibited hierarchical pore structures with remarkable high BET specific surface area of 1641.9 and 1700.2 m2 g−1, respectively. The adsorption capacities of HCP-TPP and HCP-TNP toward cationic dye methylene blue (MB) run up to 504.6 and 409.1 mg g−1 at 25 °C, respectively, but they hardly adsorbed anionic dye methyl orange (MO), exhibiting charge selectivity. The adsorption behaviors on MB were in consistence with the pseudo-second-order model and Langmuir model. The estimated thermodynamic parameters indicated the adsorption process was spontaneous and exothermic.
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