Preparation of Ricinoleic Acid from Castor Oil:A Review

蓖麻油酸 蓖麻油 化学 蓖麻属 有机化学 脂肪酶 水解 酯交换 脂肪酸
作者
Febri Odel Nitbani,Putra Jiwamurwa Pama Tjitda,Hermania Em Wogo,Annytha Ina Rohi Detha
出处
期刊:Journal of Oleo Science [Japan Oil Chemists' Society]
卷期号:71 (6): 781-793 被引量:7
标识
DOI:10.5650/jos.ess21226
摘要

Castor oil is a vegetable product extracted from Ricinus communis L (castor seed), which is primarily considered an important commercial value for the manufacturing of soaps, lubricants, coatings, etc. It is rich in hydroxylated fatty acids (ricinoleic acid, 89-92%) and is widely used in the cosmetic, pharmaceutical, oleochemical, and agricultural industries. This oil has also been confirmed as a bactericidal, anti-inflammatory, and antiherpetic agents, due to the ricinoleic acid having functional groups, such as -COOH, -OH, and -C=C-. Furthermore, it is converted into various acid derivative compounds with several applications. Therefore, this article reviewed some reaction stages to the preparation of ricinoleic acid from castor oil. Several methods or reaction pathways were employed in the preparation procedure, such as the Twitchell and Colgate-Emery processes, as well as the alkaline catalyzed, transesterification with methyl ricinoleic, and lipase-catalyzed hydrolysis, respectively. Although each of these preparation methods has advantages and disadvantages, the most effective technique was the hydrolysis through the use of the enzyme lipozyme TL IM. Besides being a green method, the conversion rate in the hydrolysis process was 96.2 ± 1.5%
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