Water-Promoted Highly Selective Anti-Markovnikov Addition of Thiols to Unactivated Alkenes
马尔科夫尼科夫法则
化学
加成反应
硫醇
有机化学
自由基加成
组合化学
区域选择性
催化作用
作者
Brindaban C. Ranu,Tanmay Mandal
出处
期刊：Synlett [Thieme Medical Publishers (Germany)] 日期：2007-03-26卷期号：2007 (6): 0925-0928被引量：60
标识
DOI：10.1055/s-2007-973877
摘要
The highly selective anti-Markovnikov addition of thiols to unactivated alkenes is demonstrated in water at room temperature without any additive. This is a very simple and efficient method for the synthesis of linear thioethers.
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