超级电容器
离子液体
氧化还原
电解质
准固态
材料科学
化学工程
电容
电化学
比能量
电极
无机化学
化学
有机化学
色素敏化染料
工程类
物理化学
物理
催化作用
量子力学
作者
Abbas Ali Hor,Neetu Yadav,S.A. Hashmi
标识
DOI:10.1016/j.est.2021.103608
摘要
Carbon supercapacitors with quasi-solid and flexible gel polymer electrolytes (GPEs) are of current interest due to their potential applicability as commercial power sources. In the recent development, improvement in specific energy of such devices is the main focus of research. Enhancement in interfacial redox-activity by adding appropriate redox-agent in electrolyte is found an excellent method to improve specific energy. In this report, a free-standing, non-aqueous, redox-active GPE is presented comprising an ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide added with additive KI, entrapped in poly(vinylidene fluoride-co-hexafluoropropylene) for its application in quasi-solid-state-supercapacitors. The optimum composition of GPE shows flexible nature, excellent mechanical and thermal stabilities with high ionic conductivity (3.9 × 10−3 S cm-1 at room temperature) and wide electrochemical stability (∼5.05 V versus Ag). Carbon supercapacitor is fabricated with redox-active GPE and symmetrical electrodes of porous activated carbon (AC) derived from waste-biomass pollen-cone. The incorporation of KI in GPE instils fast redox-activity at the AC-electrode/GPE interfaces, hence, found responsible for substantial improvement in capacitance (from ∼115 to ∼250 F g−1) and energy (from ∼31 to ∼65 Wh kg−1) at maximum power of 34–36 kW kg−1. The supercapacitor with redox-active GPE demonstrates reasonable self-discharge behavior and cycling performance with only ∼11% initial fading. The capacitor offers retention rate of ∼70% in specific capacitance and energy after ∼10,000 charge-discharge cycles.
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