双功能
材料科学
化学工程
电催化剂
电池(电)
析氧
碳纤维
无定形碳
无定形固体
催化作用
过电位
纳米技术
电极
复合数
电化学
化学
复合材料
有机化学
功率(物理)
物理化学
工程类
物理
量子力学
作者
Xiao Xiao,Wenzhi Zhang,Hui Zhao,Linfeng Li,Peichang Deng,Yulian Wu,Shuliang Luo,Beibei Chen
标识
DOI:10.1016/j.ceramint.2021.11.195
摘要
Precious metal-free bifunctional electrocatalysts with efficient performance to ORR (oxygen reduction reaction) and OER (oxygen evolution reaction) are the prerequisite to the commercialization of rechargeable Zn-air battery (RZAB). Here, ultrathin amorphous MnO2 modified prawn shells-derived porous carbon (U–MnO2/PSNC) is designed and synthesized via a self-template assisted pyrolysis coupling in-situ redox reaction strategy. In this composite, the ultrathin amorphous MnO2 provides high surface defects and homogeneous catalytic active sites. The conductive prawn shells-derived porous carbon displays macro-meso-microporous structure, promoting electric conductivity and offering fast pathway for mass diffusion. With optimized composition, the U–MnO2-0.01/PSNC delivers an excellent bifunctional to ORR/OER with a small ΔE (bifunctional activity parameter) value of 0.776 V. Moreover, the RZAB equipped with U–MnO2-0.01/PSNC displays a considerable stability with narrow decay of battery efficiency (1.10%) for ∼334 h (500 cycles) at 10 mA cm−2. This work enlightens a new pathway to design cost-effective bifunctional electrocatalysts for metal-air battery.
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