A review on the incorporation and potential mechanism of heavy metals on the recovered struvite from wastewater

Phosphorus, as a non-renewable element, is flowing out too fast in the past decades. To sustain the development of this globally scarce resource, efficient measures were taken to recover more phosphorus in the struvite form from wastewater. However, heavy metals in the wastewater might produce an inhibitory effect on phosphorus recovery, and even worse, pollutants might be incorporated in/onto the crystals precipitated. Impurities on struvite will reduce the quality of struvite as a potential slow-release fertilizer and affect the safe application of struvite in agriculture. This review aims to identify the trends in the literature to present the residues of heavy metals in struvite. It summarizes the current status in the residues of main metal elements on crystals and its response to wastewater properties, composition, and oxidation state of metals. The adsorption process and potential adsorption mechanism of heavy metals during the struvite crystallization are deeply explored, which might determine the latter release rate of metals when applying into the soil. Possible solutions are further provided to minimize the amounts of heavy metals mainly through adjusting operational conditions or employing pretreatment methods. Finally, this review critically analyzes the limitation gap between theory and actual generalization and potential application of struvite products in the market, and corresponding perspectives in the future are given to safely utilize the phosphorus resource from wastewater in the form of struvite.