Self‐Assembly Methods for Recently Reported Discrete Supramolecular Structures Based on Terpyridine

In this Review, self-assembly methods of discrete metallo-supramolecules based on 2,2' : 6',2''-terpyridine (tpy) are comprehensively summarized. With the development of self-assembly, strategies for discrete 2D and 3D supramolecular architectures have boomed, including the geometry-directed method, template-driven method, and stepwise method. Ligand geometry-directed method mainly depends on the geometry of ligands (i. e., angle, geometric strain, and rigidity), and it is suitable for dual-component systems, while the template-driven method can guide the self-assembly of predesigned supramolecules by the introduction of specific templates. Meanwhile, stepwise method, breaking the inherent self-sorting of ligands and reducing the probability of mismatch, is suitable for multicomponent systems to yield predesigned supramolecules. This review focuses on self-assembly methods and aims to provide a guideline for constructing supramolecular architectures using a suitable approach.