材料科学
环氧树脂
氮化硼
磨损(机械)
铁酸锌
阻燃剂
复合材料
复合数
硼
铁氧体(磁铁)
摩擦学
质量分数
化学工程
锌
冶金
化学
有机化学
工程类
作者
Huili Shi,Huanhuan Wang,Haitao Lu,Xia Zhang,Zhijun Zhang
出处
期刊:Langmuir
[American Chemical Society]
日期:2021-07-02
卷期号:37 (27): 8222-8231
被引量:11
标识
DOI:10.1021/acs.langmuir.1c00927
摘要
In this work, self-lubricating boron nitride nanosheets (BNNs) were decorated with flame-retardant zinc ferrite (ZnFe2O4), followed by stearic acid modification to obtain magnetic and hydrophobic properties. Under the external magnetic field, the obtained ZnFe2O4–BNNs can be well ordered into one-dimensional orientation in the epoxy resin (EP) matrix—enabling improved flame retardant properties. Compared to a randomly oriented ZnFe2O4–BNN equivalent, the well-orientated ZnFe2O4–BNNs (at 10% mass fraction) reduce the peak heat release rate and CO production by 47 and 51%, respectively. Furthermore, the ZnFe2O4–BNN/EP composite monoliths demonstrate excellent durability, displaying continued superhydrophobicity under Taber abrasion, high external pressure, knife scratch, long-term exposure to acids/bases, and harsh UV irradiation. In addition, the result shows that the well-oriented ZnFe2O4–BNN/EP composite demonstrates better tribological performance and the friction coefficient is reduced by 76.9%.
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