π–π Stacking‐Directed Crystallographic Orientation of Zn Elec‐trodeposition for Ultralong‐Life Anodes

(>480 h) and sustains stable operation for >600 h with a Zn utilization rate of 93.89%. This ALB-incorporation strategy demonstrates remarkable universality with extended lifetime across supercapacitors (>50 000 cycles), Zn||PANI full cells (>20 000 cycles at -30°C), Ah-level pouch cells (>20 cycles at 1A), and Zn-air batteries (700 h). This work provides a molecular-level pathway toward long-lasting and high-capacity Zn-based energy storage devices.