氧化剂
化学
试剂
溶解度
硝酸
无机化学
氨
酒
一氧化碳
有机化学
催化作用
作者
Kathlyn A. Parker,Dai‐Shi Su,Alexei V. Demchenko,Phillip M. Pelphrey,Dennis L. Wright,Carolyn L. Ladd
标识
DOI:10.1002/047084289x.rs024.pub4
摘要
[20667-12-3] Ag2O (MW 231.74) InChI = 1S/2Ag.O InChIKey = KHJDQHIZCZTCAE-UHFFFAOYSA-N (oxidizing reagent for conversion of hydroquinones to quinones,1 alkylphenols to quinone methides,5 and aldehydes to acids;7 oxidative coupling reactions;12, 13 a Lewis acid with halides18, 20 and thioethers;24 Wolff rearrangement26) Physical Data: dec at about 200 °C; d 7.22 g cm−3. Solubility: practically insol alcohol; sol in 40 000 parts H2O; sol dilute nitric acid, ammonia; moderately sol NaOH. Form Supplied in: brownish-black, heavy, odorless powder; widely available. Handling, Storage, and Precautions: protect from light. Reduced by hydrogen, carbon monoxide, and most metals. Skin contact with this toxic reagent should be carefully avoided.
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