化学
联苯
磺酰
级联
过渡金属
自由基环化
二氧化硫
激进的
基质(水族馆)
硫黄
光化学
级联反应
组合化学
高分子化学
有机化学
催化作用
色谱法
烷基
海洋学
地质学
作者
Nengneng Zhou,Meixia Wu,Kaimo Kuang,Sixin Wu,Man Zhang
标识
DOI:10.1002/adsc.202000999
摘要
Abstract A transition‐metal‐free photo‐induced cascade sulfonylation/addition/cyclization of 3‐arylethynyl‐[1,1′‐biphenyl]‐2‐carbonitriles with Na 2 S 2 O 5 and aryldiazonium tetrafluoroborates for the construction of 4‐sulfonated cyclopenta[ gh ]phenanthridines is developed. This reaction involves a radical pathway and goes through a sequence of phenyl radical formation, sulfur dioxide insertion, sulfonyl radical addition, iminyl radical formation, and cyclization. The methodology displays mild conditions, a broad substrate scope and does not require any external oxidants. magnified image
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