催化作用
选择性
钯
材料科学
光化学
化学
有机化学
作者
Yifei Zhang,Xiujuan Yang,Yan Zhou,Li Gao,Zhimin Li,Chao Liu,Ming Bao,Wenjie Shen
出处
期刊:Nanoscale
[The Royal Society of Chemistry]
日期:2016-01-01
卷期号:8 (44): 18626-18629
被引量:36
摘要
Pd–Au clusters of 1.8 nm preferentially catalyzed the hydrogenation of the CC bond in α,β-unsaturated aldehydes and ketones with a selectivity of ∼99%, primarily because of the unique electronic properties and isolated Pd ensembles on the ultra-small alloyed particles.
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