等结构
镧系元素
化学
发光
金属有机骨架
四氢呋喃
离子
分子
激发态
兴奋剂
苯甲酸
水溶液中的金属离子
晶体结构
光化学
结晶学
无机化学
物理化学
光电子学
材料科学
有机化学
吸附
核物理学
物理
溶剂
作者
Xinyu Wang,Yibin Xu,Qiang Huang,Yuxin Li,Guanghui An,Guangming Li
标识
DOI:10.1021/acs.analchem.8b00494
摘要
A series of isomorphic lanthanide metal–organic frameworks (Ln-MOFs), namely [Ln(dcbba)(DMF)2]n·H2O·0.5DMF [Ln = La (1), Eu (2) and Tb (3); H3dcbba = 4-(3, 5-dicarboxylatobenzyloxy)benzoic acid; DMF = N,N′-dimethylformamide] have been designed and synthesized by the solvothermal reactions of H3dcbba and La(NO3)3·6H2O. Single-crystal X-ray diffraction analysis reveals that the complexes 1–3 exhibit a (3,6)-connected open framework structure with binuclear [Ln2(COO)6]n secondary building units as 6-connected nodes and H3dcbba ligands as 3-connected nodes. The isostructural mixed La/Eu/Tb-dcbba (4) was obtained via the in-suit doping of different Ln3+ ions into the host framework, which is able to emit pure orange, white, and blue light when excited at 300, 305, and 350 nm, respectively. Subsequently, a novel and multifunctional sensing process was designed based on the excitation wavelength sensitive color tunable luminescent sample 4, which can detect HS– ions, THF (tetrahydrofuran), and Ag+ ions via different luminescence color change mechanisms. The remarkable color change, excellent selectivity, and high sensitivity further indicate the promise of this type of multifunctional luminescent materials for the sensing of anion, cation, and organic small molecule.
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