Characterizing Disorders within Cathode Materials of Lithium‐Ion Batteries

The demand for developing high‐energy density cathode materials has been increasing. The energy densities of cathode materials have been improved by adapting structural deviation from the ideal fully ordered α‐NaFeO2 type, but that led to limitations in terms of structural stability and safety. Although disorders in cathode materials are closely related to their electrochemical properties, unfortunately, characterizing the disorder itself in cathode materials has been challenging due to its complex parasitic reaction and strong correlation with other disorders occurring during charge/discharge. In this review, we categorize various disorders by their scales of ordering from short‐range to long‐range. We addressed the principles of various characterization tools to figure out how they can help to identify the structural disorder in cathode materials. Specifically, we focused on the underlying principles of each characterization technique to correlate different disorder‐driven phenomena through several case studies. It underscores the substantial importance of disorder‐property relationships and the corresponding characterization methods, which can provide novel research strategies for developing high‐energy density cathode materials with decent structural stability.