化学
羧酸盐
钪
金属有机骨架
结晶
螯合作用
金属
异羟肟酸
组合化学
无机化学
高分子化学
有机化学
吸附
作者
Wenjing Wu,Wenlei Tang,Zhen-Wu Shao,Xiaoming Feng,Lixia Xiong,Chao Xiong,Qiuxue Lai,Chong Liu
标识
DOI:10.1021/acs.inorgchem.3c04363
摘要
Starting from labile hydroxamic acid ligands that are strong chelators, here, we implemented a sacrificial modulating strategy to prepare a series of scandium carboxylate metal-organic frameworks. Overcoming conventional syntheses that use excessive carboxylate modulators, the present strategy greatly reduces the organics required and produces large single crystals of several Sc-MOFs for X-ray crystallography.
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