地质学
介观物理学
溶解
地下水
微观结构
矿物学
岩土工程
材料科学
化学工程
复合材料
物理
量子力学
工程类
作者
Qingjun Zuo,Xin He,Youyin Wu,Qinglin Yi,Shizheng Zhu,Yiliang Liu,Jian Jiang
标识
DOI:10.1144/qjegh2023-114
摘要
In radioactive waste repositories and tunnel engineering, the near-field groundwater environment is extremely complex, and changes in multiple chemical components are bound to disrupt the long-term stability of soft rock and soil, thus inducing a series of environmental and engineering geological problems. This article selects argillaceous slate as the research object and prepares different types of aqueous chemical solutions. It then conducts lateral constraint expansion tests, XRD tests, nuclear magnetic resonance tests, and SEM electron microscopy scanning tests. First, the expansion characteristics and evolution mechanism of argillaceous slate in a hydrochemical environment are revealed at the multiscale level. Then, the internal relationship between the macroscopic expansion of argillaceous slate and the microscopic and mesoscopic structures is explored. Finally, based on the experimental data and gray theory, a nonequal step GM (1, N) gray prediction model is constructed. The results indicate that (1) the water‒rock physicochemical reactions mainly affect the microstructure evolution of the argillaceous slate expansion process through pore changes, mineral dissolution, and ion exchange; (2) there is a certain correlation between the microstructure parameters and the expansion rate, and it was found that pore volume and clay mineral content are the main factors affecting the expansion of soft rocks; and (3) the model verification results show that the nonequal-step GM(1, N) gray prediction model established in this study can effectively predict the expansion trend of soft rocks in different hydrochemical environments. The research findings can provide a reference for the study of the expansion mechanism of soft rocks in complex hydrochemical environments and the disposal of expansion problems.
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