苯乙酮
钌
转移加氢
乙二醇
甲基丙烯酸酯
聚合物
共聚物
产量(工程)
化学
Noyori不对称加氢
高分子化学
催化作用
乙烯
有机化学
材料科学
冶金
作者
Stéphanie Bastin,Richard Eaves,Christopher Edwards,Osamu Ichihara,Mark Whittaker,Martin Wills
摘要
The appropriate combination of methacrylate polymers permits the synthesis of a soluble polymer for use in ruthenium(II)-catalyzed asymmetric transfer hydrogenation reactions. Using a 7:3 copolymer of a poly(ethylene glycol) ester and a hydroxyethyl ester, a derived ruthenium(II)/norephedrine complex catalyses reduction of acetophenone in up to 95% yield and 81% ee.
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