共价键
选择性
光催化
催化作用
共价有机骨架
化学
光化学
三嗪
半导体
共轭体系
复合数
吡啶
组合化学
材料科学
高分子化学
化学工程
有机化学
聚合物
光电子学
复合材料
工程类
作者
Zhihong Xu,Yao Cui,David J. Young,Jixian Wang,Hai Yan Li,Guo Qing Bian,Hong Xi Li
标识
DOI:10.1016/j.jcou.2021.101561
摘要
Pyridine CTF (CTF-Py) grafted on the surface of NH2-functionalized TiO2 (NH2-TiO2) nanoparticles gave composite TiO2@CTF-Py covalently linking the inorganic semiconductor to the nitrogen-rich porous, conjugated and coordinating organic functionality. Co2+-modified TiO2@CTF-Py was an efficient photocatalyst for the reduction of CO2 to CO with high selectivity using water as the electron donor and without exogenous photosensitizers or a sacrificial agent. The covalent connection between the semiconductors and NNN coordination group were important for this photocatalytic activity and selectivity.
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