Multifunctional nanofibrous membranes with sunlight-driven self-cleaning performance for complex oily wastewater remediation

Developing multifunctional, efficient and durable membrane for long-term usage for treating complex oily wastewater is highly desirable but still a challenge due to the severe membrane fouling. Herein, a hierarchical structured superhydrophilic/underwater superoleophobic nanofibrous with antifouling and visible-light-induced self-cleaning performance was manufactured by a facile combination of electrospun silver/β-cyclodextrin/polyacrylonitrile (Ag/β-CD/PAN) nanofibers and then the in-situ growth of a zinc oxide (ZnO) layer. The formed micro/nano sized hierarchical structure greatly increased the roughness and improved the underwater superoleophobic ability of the membrane. Therefore, the resultant ZnO/Ag/β-CD/PAN membrane displays splendid separation performance for oil/dye/water complex emulsions and high flux recovery (>90%). Meanwhile, the permeation flux of a variety of oil/water emulsions was higher than 619 L m-2h-1 with a separation efficiency above 99.7% under the action of gravity. Furthermore, the as-fabricated membrane exhibits excellent stability towards different harsh conditions (e. g. corrosive solution, high temperature, UV irradiation and ultrasound washing). The robust mechanical and chemical stability, outstanding separation capabilities as well as excellent flux recovery capabilities makes the self-cleaning membrane a good candidate for the remediation of complex oily wastewater.