羧酸盐
草酸盐
氢键
化学
离子
结晶学
三角晶系
钬
立体化学
分子
无机化学
晶体结构
物理
激光器
光学
有机化学
作者
Huilan Zhu,Hui-Ling Lai,Lu Han,Yifan Luo,Ronghua Zeng
标识
DOI:10.1107/s1600536809036344
摘要
In the title complex, {[Ho(C2O4)(C6H4NO3)(H2O)]·(H2O)}n, the HoIII ion is coordinated by three O atoms from two 2-oxidopyridinium-3-carboxylate ligands, four O atoms from two oxalate ligands and one water molecule in a distorted bicapped trigonal-prismatic geometry. The 2-oxidopyridinium-3-carboxylate and oxalate ligands link the HoIII ions into a layer in (100). These layers are further connected by intermolecular O—H⋯O hydrogen bonds involving the coordinated water molecules to assemble a three-dimensional supramolecular network. The uncoordinated water molecule is involved in N—H⋯O and O—H⋯O hydrogen bonds within the layer.
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