Nitrogen-fixing of ultrasmall Pd-based bimetallic nanoclusters on carbon supports

Abstract Synthesis of supported Pd-based bimetallic catalysts is of great importance in the heterogeneous catalysis field owing to their optimal geometric and electronic effects. Downsizing active metals to ultrasmall nanocluster ( 93% to styrene, demonstrating the alloying and small-size effects in the bimetallic nanocluster catalysts.