化学
齿合度
卤化
钯
催化作用
群(周期表)
瞬态(计算机编程)
药物化学
组合化学
有机化学
晶体结构
计算机科学
操作系统
作者
Qiyun Yong,Bing Sun,Fang‐Lin Zhang
标识
DOI:10.1016/j.tetlet.2019.151263
摘要
A facile and efficient monodentate transient directing group strategy was developed to enable the palladium-catalyzed ortho-C(sp2)H bromination of benzaldehydes. A broad scope of benzaldehydes were transformed into the desired products by employing 2-amino-5-chlorobenzotrifluoride as a monodentate transient directing group, demonstrating good functional group tolerance. Mild reaction conditions and no requirement for a silver salt are also features of this strategy.
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