水溶液
哈梅克常数
常量(计算机编程)
化学
环境化学
变化(天文学)
化学工程
有机化学
范德瓦尔斯力
计算机科学
物理
范德瓦尔斯半径
分子
天体物理学
工程类
程序设计语言
作者
Ning Tang,Ning Tang,Yihui Guo,Yongsheng Guo,Zhen Zhu,Zhen Zhu,Longbo Jiang,Longbo Jiang,Na Li,Na Li,Tingting Hu,Tingting Hu,Lixin Lu,Lixin Lu,Jingyi Zhang,Jingyi Zhang,Xiaodong Li,Xiaodong Li,Jie Liang,Jie Liang
标识
DOI:10.1021/acs.est.4c00780
摘要
The aggregation behavior of ubiquitous dissolved black carbon (DBC) largely affects the fate and transport of its own contaminants and the attached contaminants. However, the photoaging processes and resulting effects on its colloidal stability remain yet unknown. Herein, dissolved biochars (DBioCs) were extracted from common wheat straw biochar as a proxy for an anthropogenic DBC. The influences of UV radiation on their aggregation kinetics were systematically investigated under various water chemistries (pH, electrolytes, and protein). The environmental stability of the DBioCs before and after radiation was further verified in two natural water samples. Hamaker constants of pristine and photoaged DBioCs were derived according to Derjaguin-Landau-Verwey-Overbeek (DLVO) prediction, and its attenuation (3.19 ± 0.15 × 10-21 J to 1.55 ± 0.07 × 10-21 J after 7 days of radiation) was described with decay kinetic models. Pearson correlation analysis revealed that the surface properties and aggregation behaviors of DBioCs were significantly correlated with radiation time (p < 0.05), indicating its profound effects. Based on characterization and experimental results, we proposed a three-stage mechanism (contended by photodecarboxylation, photo-oxidation, and mineral exposure) that DBioCs might experience under UV radiation. These findings would provide an important reference for potential phototransformation processes and relevant behavioral changes that DBC may encounter.
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