阴极
钠
电化学
材料科学
化学工程
碳纤维
纳米技术
电极
复合数
化学
复合材料
冶金
工程类
物理化学
作者
Yongjie Cao,Xun‐Lu Li,Xiaoli Dong,Mochou Liao,Nan Wang,Jiang Cheng,Jingjun Xu,Yae Qi,Yao Liu,Yongyao Xia
出处
期刊:Small
[Wiley]
日期:2022-09-26
卷期号:18 (45)
被引量:11
标识
DOI:10.1002/smll.202204830
摘要
Sodium-ion batteries (SIBs) have attracted wide interest for energy storage because of the sufficient sodium element reserve on the earth; however, the electrochemical performance of SIBs cannot achieve the requirements so far, especially, the limitation of cathode materials. Here, a kilogram-scale route to synthesize Na2 FePO4 F/carbon/multi-walled carbon nanotubes microspheres (NFPF@C@MCNTs) composite with a high tap density of 1.2 g cm-3 is reported. The NFPF@C@MCNTs cathode exhibits a reversible specific capacity of 118.4 mAh g-1 at 0.1 C. Even under 5 C with high mass loading (10 mg cm-2 ), the specific capacity still maintains at 56.4 mAh g-1 with a capacity retention rate of 97% after 700 cycles. In addition, a hard carbon||NFPF@C@MCNTs pouch cell is assembled and tested, which exhibits a volumetric energy density of 325 Wh L-1 and gravimetrical energy density of 210 Wh kg-1 (base on electrode massing), and it provides more than 200 cycles with a capacity retention rate of 92%. Furthermore, the pouch cell can operate in an all-climate environment ranging from -40 to 80 °C. These results demonstrate that the NFPF@C@MCNTs microspheres are a promising candidate cathode for SIBs and facilitate its practical application in sodium cells.
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